This is because abs provides considerable strength, rigidity, and toughness, and abs is resistant to aqueous acids, alkalies, and animal, vegetable and mineral oils. We include information about failures and problems with some generations of plastic pipes abs, polybutylene and we describe good building practice installation details where plastic piping is being installed. Catastrophic failure occurred in a cpvc pipe through esc associated. Apache plastics defective piping was produced due to use of defective raw materials to make abs dwv between january and may 1985. Environmental cracking refers to a brittle fracture of a typical ductile material where the environments corrosive effect is the actual causing agent.
When force is applied to plastic, it travels along the polymer chains causing molecules to strain to remain in contact. The plumbing arrangements were the focus of attention by the loss adjusters and their expert figure 1, paper. Abs black plastic pipe in buildings, properties, uses, standards. The vertical section of drain vent pipe in the kitchen wall is crackedsplit along the entire footlong section from the elbow fitting in the joist cavity to the tfitting that joins the sink drain to the assembly. How to prevent stress cracking what is stress cracking. Abs plastic drainwastevent dwv pipe failure brands. Pvc pipe failure analysis applied technical services. Dimensions of abs pipes according astm d2661 standard specification for acrylonitrilebutadienestyrene abs schedule 40 plastic drain, waste, and vent pipe and. Environmental stress cracking in polyethylene takes place because of interlamellar failure, which in turn is caused by relaxation of tie molecules. Environmental stress cracking esc is one of the most common causes of unexpected brittle. However, both plastics are resistant to chemical and water degradation. Esc is a failure mechanism whereby a plastic resin is effected by a chemical agent while simultaneously under tensile loading.
Resistance to this mode of failure can be best gauged through constanttensileload testing, while taking into account the differences in yield point among various polyethylenes. The environmental stress cracking esc effects on pvc of various high ph sodium hydroxide environments have been studied. Pvc, benzene enriched natural gas, significant decrease in crazing stress. It also exhibits greater resistance to environmental stress cracking than abs, a process by which thermoplastic products undergo brittle failure due to mechanical stress and reagent attack.
Environmental stress crack resistance of polyethylene stress crack reagent concentration in the case of the most commonly used stress crack reagent, igepal co630, as the concentration of water in the stress cracking media increases, the faster the esc onset. Scott freddie torres kapl4798 june 1994 prepared for the united states department of energy prepared by knolls atomic power laboratory p. An allegedly defective plastic was used in the manufacturing of the pipe. Environmental stress cracking esc is one of the most common causes of unexpected brittle failure of thermoplastic especially amorphous polymers known at present. One such chemical that can be encountered in air conditioning and refrigeration condensate drains is polyol ester oil, commonly called poe oil, which is a type of synthetic oil used to lubricate refrigeration compressors. Plasticisers leaching from pvc can also cause esc over an extended period of. These cracks usually appear at the bends or the joints and can be detected by spotting leakages. Environmental stress cracking can be accelerated in the presence of surfaceactive substances such as. Aside from outstanding weatherability, asa also has also displayed good resistance against heat and chemical degradation. A pipe in my bathroom drainage system has developed a crack close to an elbow joint. A group of plastics made from polymers with prescribed percentages of acrylonitrile, butadiene and styrene adapter.
Environmental stress cracking can take place through continuous crack growth or via a stepwise progressive mechanism of cracking and arrest, depending on the molecular structure of the plastic, the composition of the chemical agent, the level of stress, and other environmental conditions. Abs pipe is the short name for acrylonitrile butadiene styrene pipe, which is a type of plastic pipe used in many drainage and waste water applications. A common misconception about environmental stress cracking is that it involves. Environmental stress cracking escr is the formation of cracks in a part when. Pipes carrying water will start dripping and harm their surroundings with the moisture, so it is imperative that quick and effective repair is made to avoid a. Environmental stress cracking resistance of polyethylene. Both cpvc and pvc are subject to environmental stress cracking from a variety of sources, including the chemicals used by the water treatment plant. Adhesive applications adhesive removal adhesives advanced materials cyanoacrylates environment exhibitions. Environmental stress cracking occurs in amorphous polymers such as abs, pc. With force and time, crazing or stress cracking occurs. Cracking of the acrylic sheet was typical of esc and cyclic stress. By understanding the basic structure of polyethylene, it is easy to see how this can affect environmental stress cracking. A study has been made by the author to learn effects of single and of mixed glycols causing environmental stress cracking of cpvc pipes made by four different manufacturers from two different resin suppliers.
A recent study indicated that approximately 25% of plastic component failures are associated with esc1. A secondary study also shows that the test method is appropriate for quickly evaluating chemicals in anticorrosion treatments on steel pipes in sprinkler systems that can be. Solid line corresponds to polymers where a distinct minimum is. Certain chemicals can cause environmental stress cracking esc in pvc, cpvc, and abs piping materials. Abs plastic drain wastevent dwv pipe failure brands. When the pipe stub has opened enough, grab the pipe stub with a pair of strong pliers and turn rotate spin the stub do not pull it will achieve nothing, it will peel right out of the fitting. Abs dwv pipe fittings 112 through 4 for all those situations where you need abs fittings, we offer a growing selection of many different styles and sizes. Environmental stress cracking the the chemical agent.
Stress cracking is a frequent problem in plastic applications. Abs black plastic pipe in buildings, properties, uses. Brine line and drain line tubing available for your water softener. Pvc was tested by several methods, including monotonic creep method,73. Definition of environmental stress cracking esc environmental stress cracking esc in plastics means the failure at about room temperature due to continuously acting external andor internal stresses in the presence of surface active substances known as stress cracking agents such as alcohols, soaps, dyes, agents containing moisture. Abs is one of the least resistant plastic to solvents. The result was litigation and some damage settlements, but currently it is unlikely that a homeowner will find legal relief for newlydiscovered abs drain waste vent piping cracks and failures. Environmental stress cracking can take place through continuous crack growth or via a stepwise progressive mechanism of cracking and arrest, depending on the molecular structure of the plastic, the composition of the chemical agent, the level. The craze initiation results are similar for pvc and pvccpe.
Pvc is less durable, as it is designed to be flexible and softer than usual plastics. Enhancing the environmental stress crack resistance of hdpe. Abs fittings and connectors are typically used in drain, waste, and venting applications, and are versatile options for several types of installations. The prime example is pcabs commercial for over 40 years with cycoloy. In last months article we defined the terms environmental stress cracking and solvent stress cracking, briefly explained the mechanisms involved, and provided a couple of examples of actual case studies. I would like to replace part of the pipe but keep the joint since there are 3 more joints at. Idealized stress intensity factors associated with modei crack opening under.
Test method the strain in the test environmental stress. All black hit, defective black abs plastic waste pipe manufactured in the mid 1980s failed by cracking. Fortunately, the metallurgy experts at ats can provide some detailed insight into the exact cause for plastic piping failures. Environmental stress cracking the the chemical agent does. Cracking observed on bent strip only where adhesive film was applied. In addition, some results obtained in air at lower temperatures are presented. Grace hsuan, jy zhang and wk wong department of civil, architectural and environmental engineering, drexel university, philadelphia, usa abstract the 100year stress crack resistance scr of corrugated hdpe pipes was evaluated using a 600 mm diameter pipe. This stress relaxation allows testing to run without failure for very long periods 1,500 hours. Some plastics such as abs, acrylic, polycarbonate, and polystyrene are. Environmental stress cracking and other solvent effects. The piping reportedly suffers cracking around the circumference of the pipe near joints. Special warning do not allow poe oil to come in contact with. The effect on materials exposed to an environment for a period of time, or the act of exposing materials to. Other common plastic materials used for piping include polyvinyl chloride pvc, polypropylene pp, polybutylene pb and acrylonitrilebutadienestyrene abs.
It can lead to a catastrophic breakdown or failure of a plastic material or part. We perform detailed analysis in compliance with applicable industry standards, including applicable specialized procedures such as astm d2665, standard specification for pvc drain, waste, and vent pipe and fittings. The bent strip test is a constant strain test, but polyethylene relaxes when strained. Cracking corrosion is caused by various conditions that can result in different forms of corrosion damage like. But there are methods for getting to the root of the problem. Sep, 2004 the fracture toughness of polyvinylchloride pvc and pvc modified with 10% chlorinated polyethylene pvccpe was studied in vapour and in liquid environments by crack growth measurements on singleedge notch specimens under threepoint bending at 23c. It is the combination of stress and fluid contact that causes failure to occur much earlier than either component could achieve in isolation, if at all. Abs drain pipe material failures were reported for pipe made between 1985 and 1988. The study has shown that a mixture of ethylene glycol and propylene glycol is more damaging to cpvc pipe than either of the glycols by. Throughout a semicrystalline polymer, there may be small packets of crystals contained within the amorphous matrix, with some polymer chains being so long that they can be in two different crystals at the same time. Dunbar ky this topic of convo showed up on another corner of the web recently and it was told that abs piping had a problem with cracking in this fashion. Environmental stress cracking esc is not the result of the continual battle that the plastics industry has in convincing environmentalists and politicians that plastics can be the solution to environmental problems and not the cause.
Bad abs pipe of the 80s i was the primary plumbing contractor replacing defective abs pipe in over 80 homes in the simi valley in the early 90s and that is the proper way to make the repairs. Plastic which does not meet the material requirements specified in section 5 is excluded. A fitting that joins two different pipes together or one that joins threaded with nonthreaded pipe aging. Plumbermandan ia i just replaced a piece of abs on a kitchen drain just like that, cracked the entire length on the 2 line, it was a small leak but it was annoying. Environmental stress cracking esc is not the result of the continual battle that the plastics industry has in convincing environmentalists and politicians that plastics can be the solution to environmental problems and not the cause esc is the consequence of a combination of mechanical stress and exposure to an aggressive chemical. Abs pipe has become very popular among builders because of its light weight, which makes it easy to transport, and its cheap price. Abs piping is most often found in secondary cooling and refrigeration applications, sewer systems, and drainwastevent dwv pipe systems. Environmental stress cracking of polyvinyl chloride in. When bonding pvc to polystyrene, the plasticizers in the pvc can leach. Environmental stress crack resistance of polyethylene today, this test is specified less frequently because it is not as aggressive towards modern resins. This helps to make a clean dry surface for solvent bonding. Because of this, environmental stress cracking and creep rupture are parallel failure mechanisms. Open the wall nicely replace the pipe, you will have to open the wall to patch it so why not replace it and be rid of the headache.
Jun 02, 2005 drain nothing lasts forever, even a lifetime water heater will fail at least once, and more than likely several times. Unfortunately, even the best quality piping is susceptible to clogging and abs is no exception. Environmental stress crack resistance of polyethylene. Environmental stress cracking, often referred to as esc, causes a stressed plastics part to become brittle and crack when in contact with a wide range of fluids that act as stress cracking agents. The vertical section of drainvent pipe in the kitchen wall is crackedsplit along the entire footlong section from the elbow fitting in the joist cavity to the tfitting that joins the sink drain to the assembly. Residual stresses and stress corrosion cracking in pipe fittings ronald j. An abs pipe can develop cracks in its surface due to increased stress, inappropriate temperature or just due to usage over a period of time. Astm d2661 acrylonitrilebutadienestyrene abs schedule. Abs is a tough plastic susceptible to such cracking, often under unusual circumstances. Environmental stress cracking esc is widely regarded as the leading cause of plastic product failure. Cpvc and pvc pipes are designed to last for decades, there are certain environmental factors that can cause them to fail prematurely. Cracks that develop when a plastic part is subjected to incompatible chemicals and put under stress extrusion.
Place a drip pan under the abs pipe to catch dripping water. Butadiene styrene abs plastic couplings plastic couplings installed as part of a water closet carrier system were found to be leaking in many of the rooms of a localfound to be leaking in many of the rooms of a local. The polymer chains eventually creep toward the pull and deform. The craze initiation stress is decreased dramatically at high benzene concentrations. The pipe is inconveniently located behind my furnace and water heater so i had to go through the drywall in my utility room to access it. The fracture toughness is quantified by a stress intensity. The craze initiation stress is decreased dramatically at high benzene. Environmental stress cracking follows several tendencies regarding all three of the essential eleseveral molded plastic housings utilized in a commercial sprinkler application failed shortly after installation. This month we want to conclude the discussion with a few more case studies and then discuss tests and material selection techniques that can keep us out of trouble with this. The strain in the test environmental stress cracking of plastics h. Abs dwv drainage fittings drainage fittings drainage. Environmental stress cracking is a physical phenomenon that is initiated as a slow surface crack. Environmental stress cracking of commercial cpvc pipes. Abs waste drainage system ryan herco flow solutions.
The housings were molding from a polyacrylonitrile. Plastic failure through environmental stress cracking. The material was removed from store shelves about 5 years ago and is impossible to find in my area for those who used it. The study also showed that one pipe resin containing a tail of lower molecular weight resin is somewhat more susceptible to cracking than the other resin.
According to astm d883, stress cracking is defined as an external or internal crack in a plastic caused by tensile stresses less than its shortterm mechanical strength. What i have found is that it only leaks when mass quantities of water are flushed through it. Failure analysis methodology scheirs 2000 determination of resistance to environmental stress cracking esc iso 220883. The failures in these piping systems occurred only in pipes manufactured in 1985 and, to a lesser extent, in 1986. Pipes carrying water will start dripping and harm their surroundings with the moisture, so it is imperative that quick and effective repair is made to. Pex pipe tubing pex or crosslinked polyethylene is part of a water supply piping system that has several advantages over metal pipe copper, iron, lead or rigid plastic pipe pvc, cpvc, abs systems.
This is abs pipe to join with old cast iron pipe, it sits half an inch below floor. Copper is susceptible to failure from chemicals poured into the drain, cast iron develops stactites and stalagmites inside from rust, galvanized can close down from rust accumulations, abs or pvc can crack from stress or poor installation. Cut the damaged pipe with pipe cutters or a hacksaw. Apr 02, 2018 it also exhibits greater resistance to environmental stress cracking than abs, a process by which thermoplastic products undergo brittle failure due to mechanical stress and reagent attack. To avoid problems, select your material with care and employ the fundamental rules of good design and processing. Standard specification for acrylonitrilebutadienestyrene. Li b a department of macromolecular science and the key laboratory of molecular engineering of polymers, fudan university, shanghai, 200433, china b shanghai koito automotive lamp co. The 2nd is the joist cavity just below the kitchen. Esc is the consequence of a combination of mechanical stress and exposure to an aggressive chemical. Craze initiation, craze growth and ultimate fracture were studied in pvc polyvinylchloride and pvccpe pvc blend with 10% chlorinated polyethylene under a constant load in air and in natural gas enriched with benzene. According to astm d883, stress cracking is defined as an external or internal crack in a plastic caused by tensile stresses less than its shortterm mechanical.
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