An allegedly defective plastic was used in the manufacturing of the pipe. Esc is the consequence of a combination of mechanical stress and exposure to an aggressive chemical. Astm d2661 acrylonitrilebutadienestyrene abs schedule. The effect on materials exposed to an environment for a period of time, or the act of exposing materials to.
This is because abs provides considerable strength, rigidity, and toughness, and abs is resistant to aqueous acids, alkalies, and animal, vegetable and mineral oils. Environmental stress cracking follows several tendencies regarding all three of the essential eleseveral molded plastic housings utilized in a commercial sprinkler application failed shortly after installation. Environmental stress cracking of polyvinyl chloride in. The study also showed that one pipe resin containing a tail of lower molecular weight resin is somewhat more susceptible to cracking than the other resin. Environmental stress cracking escr is the formation of cracks in a part when. The polymer chains eventually creep toward the pull and deform. The 2nd is the joist cavity just below the kitchen. Dimensions of abs pipes according astm d2661 standard specification for acrylonitrilebutadienestyrene abs schedule 40 plastic drain, waste, and vent pipe and. When bonding pvc to polystyrene, the plasticizers in the pvc can leach. Catastrophic failure occurred in a cpvc pipe through esc associated. This helps to make a clean dry surface for solvent bonding. Plasticisers leaching from pvc can also cause esc over an extended period of. The plumbing arrangements were the focus of attention by the loss adjusters and their expert figure 1, paper.
When force is applied to plastic, it travels along the polymer chains causing molecules to strain to remain in contact. Abs drain pipe material failures were reported for pipe made between 1985 and 1988. Standard specification for acrylonitrilebutadienestyrene. The craze initiation stress is decreased dramatically at high benzene concentrations.
Resistance to this mode of failure can be best gauged through constanttensileload testing, while taking into account the differences in yield point among various polyethylenes. Li b a department of macromolecular science and the key laboratory of molecular engineering of polymers, fudan university, shanghai, 200433, china b shanghai koito automotive lamp co. This stress relaxation allows testing to run without failure for very long periods 1,500 hours. Plumbermandan ia i just replaced a piece of abs on a kitchen drain just like that, cracked the entire length on the 2 line, it was a small leak but it was annoying. It also exhibits greater resistance to environmental stress cracking than abs, a process by which thermoplastic products undergo brittle failure due to mechanical stress and reagent attack. The material was removed from store shelves about 5 years ago and is impossible to find in my area for those who used it. The mechanisms of environmental stress cracking proposed in the literature will be.
Environmental stress crack resistance of polyethylene stress crack reagent concentration in the case of the most commonly used stress crack reagent, igepal co630, as the concentration of water in the stress cracking media increases, the faster the esc onset. Environmental stress cracking the the chemical agent. Environmental stress cracking can take place through continuous crack growth or via a stepwise progressive mechanism of cracking and arrest, depending on the molecular structure of the plastic, the composition of the chemical agent, the level. A study has been made by the author to learn effects of single and of mixed glycols causing environmental stress cracking of cpvc pipes made by four different manufacturers from two different resin suppliers. The vertical section of drain vent pipe in the kitchen wall is crackedsplit along the entire footlong section from the elbow fitting in the joist cavity to the tfitting that joins the sink drain to the assembly.
Environmental stress cracking can take place through continuous crack growth or via a stepwise progressive mechanism of cracking and arrest, depending on the molecular structure of the plastic, the composition of the chemical agent, the level of stress, and other environmental conditions. Adhesive applications adhesive removal adhesives advanced materials cyanoacrylates environment exhibitions. Environmental stress cracking can be accelerated in the presence of surfaceactive substances such as. Cracking corrosion is caused by various conditions that can result in different forms of corrosion damage like. Certain chemicals can cause environmental stress cracking esc in pvc, cpvc, and abs piping materials. The bent strip test is a constant strain test, but polyethylene relaxes when strained.
Abs fittings and connectors are typically used in drain, waste, and venting applications, and are versatile options for several types of installations. Copper is susceptible to failure from chemicals poured into the drain, cast iron develops stactites and stalagmites inside from rust, galvanized can close down from rust accumulations, abs or pvc can crack from stress or poor installation. Craze initiation, craze growth and ultimate fracture were studied in pvc polyvinylchloride and pvccpe pvc blend with 10% chlorinated polyethylene under a constant load in air and in natural gas enriched with benzene. Open the wall nicely replace the pipe, you will have to open the wall to patch it so why not replace it and be rid of the headache. The pipe is inconveniently located behind my furnace and water heater so i had to go through the drywall in my utility room to access it. Brine line and drain line tubing available for your water softener. Plastic failure through environmental stress cracking.
Pvc is less durable, as it is designed to be flexible and softer than usual plastics. To avoid problems, select your material with care and employ the fundamental rules of good design and processing. Abs waste drainage system ryan herco flow solutions. Environmental stress cracking the the chemical agent does. Environmental stress cracking esc is not the result of the continual battle that the plastics industry has in convincing environmentalists and politicians that plastics can be the solution to environmental problems and not the cause esc is the consequence of a combination of mechanical stress and exposure to an aggressive chemical. Pvc, benzene enriched natural gas, significant decrease in crazing stress. Plastic which does not meet the material requirements specified in section 5 is excluded. Cut the damaged pipe with pipe cutters or a hacksaw. Other common plastic materials used for piping include polyvinyl chloride pvc, polypropylene pp, polybutylene pb and acrylonitrilebutadienestyrene abs. Fortunately, the metallurgy experts at ats can provide some detailed insight into the exact cause for plastic piping failures. Aside from outstanding weatherability, asa also has also displayed good resistance against heat and chemical degradation. However, both plastics are resistant to chemical and water degradation. A secondary study also shows that the test method is appropriate for quickly evaluating chemicals in anticorrosion treatments on steel pipes in sprinkler systems that can be.
Test method the strain in the test environmental stress. This month we want to conclude the discussion with a few more case studies and then discuss tests and material selection techniques that can keep us out of trouble with this. Pex pipe tubing pex or crosslinked polyethylene is part of a water supply piping system that has several advantages over metal pipe copper, iron, lead or rigid plastic pipe pvc, cpvc, abs systems. The prime example is pcabs commercial for over 40 years with cycoloy. In last months article we defined the terms environmental stress cracking and solvent stress cracking, briefly explained the mechanisms involved, and provided a couple of examples of actual case studies. A common misconception about environmental stress cracking is that it involves. All black hit, defective black abs plastic waste pipe manufactured in the mid 1980s failed by cracking.
Bad abs pipe of the 80s i was the primary plumbing contractor replacing defective abs pipe in over 80 homes in the simi valley in the early 90s and that is the proper way to make the repairs. This is abs pipe to join with old cast iron pipe, it sits half an inch below floor. Abs is a tough plastic susceptible to such cracking, often under unusual circumstances. The failures in these piping systems occurred only in pipes manufactured in 1985 and, to a lesser extent, in 1986. Pipes carrying water will start dripping and harm their surroundings with the moisture, so it is imperative that quick and effective repair is made to avoid a.
Jun 02, 2005 drain nothing lasts forever, even a lifetime water heater will fail at least once, and more than likely several times. The strain in the test environmental stress cracking of plastics h. Environmental stress cracking esc is widely regarded as the leading cause of plastic product failure. Pvc was tested by several methods, including monotonic creep method,73. How to prevent stress cracking what is stress cracking. Solid line corresponds to polymers where a distinct minimum is. Abs black plastic pipe in buildings, properties, uses. Cracks that develop when a plastic part is subjected to incompatible chemicals and put under stress extrusion. An abs pipe can develop cracks in its surface due to increased stress, inappropriate temperature or just due to usage over a period of time.
Abs plastic drainwastevent dwv pipe failure brands. Abs dwv drainage fittings drainage fittings drainage. Environmental stress crack resistance of polyethylene today, this test is specified less frequently because it is not as aggressive towards modern resins. Environmental stress cracking esc is one of the most common causes of unexpected brittle failure of thermoplastic especially amorphous polymers known at present. One such chemical that can be encountered in air conditioning and refrigeration condensate drains is polyol ester oil, commonly called poe oil, which is a type of synthetic oil used to lubricate refrigeration compressors. A recent study indicated that approximately 25% of plastic component failures are associated with esc1. Abs pipe is the short name for acrylonitrile butadiene styrene pipe, which is a type of plastic pipe used in many drainage and waste water applications. Cpvc and pvc pipes are designed to last for decades, there are certain environmental factors that can cause them to fail prematurely. Environmental stress cracking occurs in amorphous polymers such as abs, pc. The housings were molding from a polyacrylonitrile. A pipe in my bathroom drainage system has developed a crack close to an elbow joint. Esc is a failure mechanism whereby a plastic resin is effected by a chemical agent while simultaneously under tensile loading. We perform detailed analysis in compliance with applicable industry standards, including applicable specialized procedures such as astm d2665, standard specification for pvc drain, waste, and vent pipe and fittings. According to astm d883, stress cracking is defined as an external or internal crack in a plastic caused by tensile stresses less than its shortterm mechanical strength.
Place a drip pan under the abs pipe to catch dripping water. The study has shown that a mixture of ethylene glycol and propylene glycol is more damaging to cpvc pipe than either of the glycols by. The craze initiation stress is decreased dramatically at high benzene. Apache plastics defective piping was produced due to use of defective raw materials to make abs dwv between january and may 1985.
Environmental stress cracking resistance of polyethylene. Throughout a semicrystalline polymer, there may be small packets of crystals contained within the amorphous matrix, with some polymer chains being so long that they can be in two different crystals at the same time. Some plastics such as abs, acrylic, polycarbonate, and polystyrene are. Environmental stress cracking of commercial cpvc pipes. Definition of environmental stress cracking esc environmental stress cracking esc in plastics means the failure at about room temperature due to continuously acting external andor internal stresses in the presence of surface active substances known as stress cracking agents such as alcohols, soaps, dyes, agents containing moisture. Abs black plastic pipe in buildings, properties, uses, standards. The environmental stress cracking esc effects on pvc of various high ph sodium hydroxide environments have been studied. The fracture toughness is quantified by a stress intensity. With force and time, crazing or stress cracking occurs. When the pipe stub has opened enough, grab the pipe stub with a pair of strong pliers and turn rotate spin the stub do not pull it will achieve nothing, it will peel right out of the fitting. Environmental stress cracking esc is one of the most common causes of unexpected brittle. A group of plastics made from polymers with prescribed percentages of acrylonitrile, butadiene and styrene adapter. Unfortunately, even the best quality piping is susceptible to clogging and abs is no exception.
It can lead to a catastrophic breakdown or failure of a plastic material or part. Environmental stress cracking and other solvent effects. The craze initiation results are similar for pvc and pvccpe. Environmental stress cracking, often referred to as esc, causes a stressed plastics part to become brittle and crack when in contact with a wide range of fluids that act as stress cracking agents. Cracking observed on bent strip only where adhesive film was applied.
Failure analysis methodology scheirs 2000 determination of resistance to environmental stress cracking esc iso 220883. We include information about failures and problems with some generations of plastic pipes abs, polybutylene and we describe good building practice installation details where plastic piping is being installed. Because of this, environmental stress cracking and creep rupture are parallel failure mechanisms. Environmental cracking refers to a brittle fracture of a typical ductile material where the environments corrosive effect is the actual causing agent. But there are methods for getting to the root of the problem. Stress cracking is a frequent problem in plastic applications. Environmental stress cracking esc is not the result of the continual battle that the plastics industry has in convincing environmentalists and politicians that plastics can be the solution to environmental problems and not the cause. Dunbar ky this topic of convo showed up on another corner of the web recently and it was told that abs piping had a problem with cracking in this fashion.
These cracks usually appear at the bends or the joints and can be detected by spotting leakages. Scott freddie torres kapl4798 june 1994 prepared for the united states department of energy prepared by knolls atomic power laboratory p. Abs piping is most often found in secondary cooling and refrigeration applications, sewer systems, and drainwastevent dwv pipe systems. According to astm d883, stress cracking is defined as an external or internal crack in a plastic caused by tensile stresses less than its shortterm mechanical.
Abs is one of the least resistant plastic to solvents. Special warning do not allow poe oil to come in contact with. Environmental stress cracking in polyethylene takes place because of interlamellar failure, which in turn is caused by relaxation of tie molecules. Abs plastic drain wastevent dwv pipe failure brands. Apr 02, 2018 it also exhibits greater resistance to environmental stress cracking than abs, a process by which thermoplastic products undergo brittle failure due to mechanical stress and reagent attack. Both cpvc and pvc are subject to environmental stress cracking from a variety of sources, including the chemicals used by the water treatment plant. Enhancing the environmental stress crack resistance of hdpe. The piping reportedly suffers cracking around the circumference of the pipe near joints. Residual stresses and stress corrosion cracking in pipe fittings ronald j. Abs dwv pipe fittings 112 through 4 for all those situations where you need abs fittings, we offer a growing selection of many different styles and sizes. Idealized stress intensity factors associated with modei crack opening under. I would like to replace part of the pipe but keep the joint since there are 3 more joints at. What i have found is that it only leaks when mass quantities of water are flushed through it.
Pvc pipe failure analysis applied technical services. It is the combination of stress and fluid contact that causes failure to occur much earlier than either component could achieve in isolation, if at all. Grace hsuan, jy zhang and wk wong department of civil, architectural and environmental engineering, drexel university, philadelphia, usa abstract the 100year stress crack resistance scr of corrugated hdpe pipes was evaluated using a 600 mm diameter pipe. The vertical section of drainvent pipe in the kitchen wall is crackedsplit along the entire footlong section from the elbow fitting in the joist cavity to the tfitting that joins the sink drain to the assembly. Pipes carrying water will start dripping and harm their surroundings with the moisture, so it is imperative that quick and effective repair is made to. Cracking of the acrylic sheet was typical of esc and cyclic stress.
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